重量法测定镍矿中的氧化镁     

郝原芳  徐英奎  张扩 《地质与资源》2014,23(4):395-397

建立镍矿中测定氧化镁的分析方法,采用磷酸氢二铵形成磷酸铵镁沉淀来计算氧化镁的质量分数.研究镍的存在形式、温度、沉淀剂、陈化时间、干扰元素对结果的影响.最佳条件为灼烧温度1100℃,沉淀剂用量20 mL,陈化时间5 h以上.方法检出限为1%,相对标准偏差0.31%~4.38%,回收率98.9%~100.3%.本方法准确度高,操作简单,适合镍矿中氧化镁的测定.  相似文献   

用VC开发Windows字符曲线类   总被引：4，自引：4，他引：0  

陆玲  汤彬 《物探化探计算技术》2000,22(3):282-286

作者用ＶｉｓｕａｌＣ＾＋＋６．０与ＭＦＣ开发了一个Ｗｉｎｄｏｗｓ图形应用类。该类可实现沿曲线方向书写用户指定的字符串,增强了ＣＤＣ类的绘制功能,为今后用ＶＣ开发专用图形软件提供了有利帮助。  相似文献   

Tracer and hydrometric study of preferential flow in large undisturbed soil cores from the Georgia Piedmont,USA     

Janice McIntosh  Jeffrey J. McDonnell  Norman E. Peters 《水文研究》1999,13(2):139-155

We studied the temporal patterns of tracer throughput in the outflow of large (30 cm diameter by 38 cm long) undisturbed cores from the Panola Mountain Research Watershed, Georgia. Tracer breakthrough was affected by soil structure and rainfall intensity. Two rainfall intensities (20 and 40 mm hr⁻¹) for separate Cl⁻ and Br⁻ amended solutions were applied to two cores (one extracted from a hillslope soil and one extracted from a residual clay soil on the ridge). For both low and high rainfall intensity experiments, preferential flow occurred in the clay core, but not in the hillslope core. The preferential flow is attributed to well‐developed interpedal macrochannels that are commonly found in structured clay soils, characteristic of the ridge site. However, each rainfall intensity exceeded the matrix infiltration capacity at the top of the hillslope core, but did not exceed the matrix infiltration capacity at the middle and bottom of the hillslope core and at all levels in the clay core. Localized zones of saturation created when rainfall intensity exceeds the matrix infiltration capacity may cause water and tracer to overflow from the matrix into macrochannels, where preferential flow occurs to depth in otherwise unsaturated soil. Copyright © 1999 John Wiley & Sons, Ltd.  相似文献   

乙酸铵交换-全自动凯氏定氮法测定贵州某地区耕地土壤阳离子交换量          下载免费PDF全文

邓昭祥  钟蕾  况云所  邓云江  杜作灵  张安丰  杨健  张舟 《贵州地质》2020,37(4):558-562

：为分析无机结合料稳定铁尾矿用作半刚性路面基层的水稳定性,对铁尾矿进行筛分,通过测定改良铁尾矿混合料的液限、塑限,确定无机结合料稳定类型,按二级及二级以下公路路面基层的集料级配要求改良铁尾矿,以击实试验确定无机结合料稳定时最佳含水率和最大干密度,然后用半刚性基层冲刷量灰色预估模型计算并分析其抗冲刷性。结果表明：铁尾矿为特细集料,液限为19%,塑性指数为11,宜采用水泥进行稳定,掺加级配碎石改良铁尾矿满足CC3集料级配要求,当水泥剂量为5%时能够取得良好的抗冲刷性能和经济性。  相似文献   

基于次溴酸钠氧化-氨基磺酸还原测定沉积物15N加富培养样品中的15NH+4的方法探索     

徐颢铭  宋国栋  刘素美  梁生康  张桂玲 《海洋学报》2022,44(1):147-154

沉积物中的异化硝酸盐还原过程是海洋中活性氮转化的关键过程之一.不同于反硝化和厌氧铵氧化,异化硝酸盐还原为铵(DNRA)是将硝酸盐直接还原为铵,而不是以氮气的形态移除,这有可能会加重水体富营养化和缺氧.目前测定沉积物中异化硝酸盐还原过程的主要手段是15N标记培养技术.为了准确评估DNRA的潜在速率,首先要准确测定加富样品...  相似文献   

Evaluating equilibrium and non‐equilibrium transport of ammonium in a loam soil column          下载免费PDF全文

Lizhu Hou  Bill X. Hu  Zhiming Qi  Huan Yang 《水文研究》2018,32(1):80-92

Release of nitrogen compounds into groundwater, particularly those compounds from excessive agricultural fertilization, is a major concern in an aquifer recharge. Among the nitrogen compounds, ammonium ( ) is a common one. In order to assess the risk of agricultural fertilizer contamination to an aquifer through infiltration, adsorption onto a loamy agricultural soil profile (0–0.60 m depth) was studied using a soil column experiment and modelling simulation. The soil used in the experiment was drawn from an agricultural field in Xinzhen, Fangshan district, Beijing, China, and reconstituted in laboratory soil columns. Column experiments were conducted using bromide (conservative tracer) and ‐bearing aqueous solutions. The ammonium concentrations in the soil water samples were measured, and their values were plotted as the breakthrough curves. The chemical's soil–water distribution coefficients (K_d) were calculated using breakthrough curves. Then the retardation factor (R) in saturated soil was calculated. For the ‐bearing aqueous solutions, the strongest adsorption occurred at the soil depth of 0.30–0.45 m. The convection–dispersion equation model and chemical non‐equilibrium model in Hydrus‐1D were used to simulate transport in the loamy soil. The two‐site chemical non‐equilibrium model in Hydrus‐1D was best to simulate transport through the soil column. Parameter sensitivity study was conducted to investigate the influences of solute transport by K_d, the fraction of exchange sites assuming to be in equilibrium with the solution phase (f), the longitudinal dispersivity (λ), and the first‐order rate coefficients (ω). The sensitivity analysis results indicate K_d is the most critical parameter.  相似文献   

太湖霍甫水丝蚓(Limnodrilus hoffmeisteri) NH₄⁺-N和PO₄^3--P的潜在释放量     

龚志军  刘劲松  李艳  蔡永久  薛庆举  许浩 《湖泊科学》2017,29(2):389-397

为了研究太湖底栖动物优势种类——霍甫水丝蚓(Limnodrilus hoffmeisteri)对于湖泊富营养化的影响,以温度和密度为模拟控制条件,对太湖霍甫水丝蚓进行营养盐释放的室内控制实验,研究温度和密度的变化对霍甫水丝蚓NH_4~+-N和PO_4~(3-)-P释放率的影响,根据霍甫水丝蚓铵态氮(NH_4~+-N)和磷酸盐(PO_4~(3-)-P)释放率与温度的关系方程,结合太湖霍甫水丝蚓2007-2010年的生物量估算其对太湖水体氮磷的潜在贡献.结果表明,随温度升高太湖霍甫水丝蚓NH_4~+-N和PO_4~(3-)-P的释放率均呈现逐渐升高的趋势,而密度变化对霍甫水丝蚓NH_4~+-N和PO_4~(3-)-P释放率的影响均不显著,太湖霍甫水丝蚓NH_4~+-N和PO_4~(3-)-P年平均释放量分别为1925.5和210.0 t,分别可达到全太湖沉积物-水界面NH_4~+-N和PO_4~(3-)-P的年净通量的19.3%和23.3%,表明霍甫水丝蚓的营养盐释放对于湖泊生物地化循环和湖泊富营养化具有显著的影响.  相似文献   

X-ray Diffraction of Dust Particles in Spring Beijing   总被引：1，自引：1，他引：0  

ZHENG Nan  WANG Hejin  XU Tingjing  LI Ting 《《地质学报》英文版》2011,85(1):254-262

X-ray diffractometry was utilized to study the mineralogical characteristics of the inhalable particles (PM10) sampled during two dust storms in Beijing city on March 18th and May 21st, 2008. We confirm, for the first time, that there stably exists ammonium chloride in the atmosphere when temperature is low. The total sulfates particles were affected by relative humidity. Both species and concentration of sulfates decreased first and then grew back by the end of each dust storm. Koninckite, a phosphate mineral never reported as particulate aerosol before, was identified. Meanwhile, our result shows that a chemical modification on dust minerals occurs during long range transportation. PM10 samples collected during the period of dust storms were dominated by crustal minerals such as quartz, illite/ smectite, illite, chlorite, feldspar and calcite, and were notably higher in concentration than that in normal periods of time. The amounts of total sulfates, calcite and feldspar altered in each dust storm. It is derived from 24-hour isentropic backward trajectories that two dust events in spring 2008 originated in different sources.  相似文献   

乌鲁木齐河源1号冰川雪-冰界面含氮离子迁移研究     

王圣杰  张明军  王飞腾  李忠勤  张晓宇 《地球学报》2011,32(6):699-706

冰川积累区雪-冰界面附近的化学物质迁移对冰芯记录的形成具有重要意义,为讨论主要含氮离子在这一界面的迁移,本研究基于2004年11月至2006年3月在天山乌鲁木齐河源1号冰川连续采集的64组雪冰样品分析了NO3与NH4+的变化情况.结果表明,雪层底部干季(11月至翌年3月)含氮离子浓度的平均值高于湿季(4-10月)的,而...  相似文献   

海洋环境中的厌氧氨氧化细菌与厌氧氨氧化作用     

姚鹏  于志刚 《海洋学报(英文版)》2011,30(4):1-8

厌氧氨氧化是细菌在厌氧条件下将氨氮氧化成氮气的过程,主要应用在污水处理反应器中,最近几年发现在海洋环境中也广泛存在,并在海洋氮循环过程中发挥了重要作用,代表了海洋中一个巨大的氮汇,对碳循环和全球气候变化也有重要影响。梯烷膜脂结构独特,是厌氧氨氧化细菌的化学生物标志物,具有化学分类与古海洋学应用潜力。厌氧氨氧化作用及厌氧氨氧化细菌已成为海洋生物地球化学、微生物学、有机地球化学等研究领域的热点。  相似文献